Frost flower influence on springtime boundary-layer ozone depletion events and atmospheric bromine levels

Halogens and polar boundary-layer ozone depletion

1 Geophysical Institute and Department of Chemistry, University of Alaska Fairbanks, Fairbanks, AK, 99775-6160, USA 2 School of Environmental Sciences, University of East Anglia, Norwich, NR4 7TJ, UK 3 National Institute of Water and Atmospheric Research, Private Bag 14–901, Wellington, New Zealand 4 British Antarctic Survey, High Cross, Madingley Road, Cambridge CB3 0ET, UK 5 McGill University...

Coupled evolution of BrOx-ClOx-HOx-NOx chemistry during bromine- catalyzed ozone depletion events in the arctic boundary layer

[1] Extensive chemical characterization of ozone (O3) depletion events in the Arctic boundary layer during the TOPSE aircraft mission in March–May 2000 enables analysis of the coupled chemical evolution of bromine (BrOx), chlorine (ClOx), hydrogen oxide (HOx) and nitrogen oxide (NOx) radicals during these events. We project the TOPSE observations onto an O3 chemical coordinate to construct a ch...

The potential importance of frost flowers, recycling on snow, and open leads for Ozone Depletion Events

We present model studies with the one-dimensional model MISTRA to investigate the potential role of frost flowers, recycling on snow, and open leads in the depletion of tropospheric ozone in the Arctic spring. In our model, we assumed frost flower aerosols to be the major source of bromine. We show that a major ozone depletion event can be satisfactorily reproduced only if the recycling on snow...

Halogens and their role in polar boundary-layer ozone depletion

During springtime in the polar regions, unique photochemistry converts inert halide salt ions (e.g. Br) into reactive halogen species (e.g. Br atoms and BrO) that deplete ozone in the boundary layer to near zero levels. Since their discovery in the late 1980s, research on ozone depletion events (ODEs) has made great advances; however many key processes remain poorly understood. In this article ...

Ozone Layer Depletion